摘要：

The aim of this study was to determine the thermodynamics of the solvation of CaSOin mixed DMF-HO at 301.15 K. The Gibbs free energies as very important thermodynamic property were evaluated for CaSOin mixed dimethylformamide (DMF)-HO solvents at 301.15 K from the experimental solubility measurements. The ratio of the ionic radii between calcium and sulphate ions was used to divide the total Gibbs free energy of the salt into its individual contribution in the mixtures used. Libration Gibbs free energy associated with the moving CaSOin standard gas state to standard state in solution was evaluated according to specific cycle for the solvation process using the solubility product. Also the lattice energy for solid CaSO(cr) was also calculated and used for further evaluation. The conventional Gibbs free energies for the cation (Ca) and the anion (SO) were estimated theoretically and also the Gibbs free energy of SOgas was evaluated and all values were discussed.

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