簡單制作單高斯和的參數化模型函數。為最初的猜測選擇一個好的值(這是一個非常關鍵的步驟)，然后讓scipy.optimize稍微調整一下這些數字。

你可以這樣做：import numpy as np

import matplotlib.pyplot as plt

from scipy import optimize

data = np.genfromtxt('data.txt')

def gaussian(x, height, center, width, offset):

return height*np.exp(-(x - center)**2/(2*width**2)) + offset

def three_gaussians(x, h1, c1, w1, h2, c2, w2, h3, c3, w3, offset):

return (gaussian(x, h1, c1, w1, offset=0) +

gaussian(x, h2, c2, w2, offset=0) +

gaussian(x, h3, c3, w3, offset=0) + offset)

def two_gaussians(x, h1, c1, w1, h2, c2, w2, offset):

return three_gaussians(x, h1, c1, w1, h2, c2, w2, 0,0,1, offset)

errfunc3 = lambda p, x, y: (three_gaussians(x, *p) - y)**2

errfunc2 = lambda p, x, y: (two_gaussians(x, *p) - y)**2

guess3 = [0.49, 0.55, 0.01, 0.6, 0.61, 0.01, 1, 0.64, 0.01, 0] # I guess there are 3 peaks, 2 are clear, but between them there seems to be another one, based on the change in slope smoothness there

guess2 = [0.49, 0.55, 0.01, 1, 0.64, 0.01, 0] # I removed the peak I'm not too sure about

optim3, success = optimize.leastsq(errfunc3, guess3[:], args=(data[:,0], data[:,1]))

optim2, success = optimize.leastsq(errfunc2, guess2[:], args=(data[:,0], data[:,1]))

optim3

plt.plot(data[:,0], data[:,1], lw=5, c='g', label='measurement')

plt.plot(data[:,0], three_gaussians(data[:,0], *optim3),

lw=3, c='b', label='fit of 3 Gaussians')

plt.plot(data[:,0], two_gaussians(data[:,0], *optim2),

lw=1, c='r', ls='--', label='fit of 2 Gaussians')

plt.legend(loc='best')

plt.savefig('result.png')

如您所見，這兩種配合(視覺上)幾乎沒有區別。所以你不能確定源中是否有3個高斯子，或者只有2個高斯子。但是，如果您必須進行猜測，請檢查最小的殘差：err3 = np.sqrt(errfunc3(optim3, data[:,0], data[:,1])).sum()

err2 = np.sqrt(errfunc2(optim2, data[:,0], data[:,1])).sum()

print('Residual error when fitting 3 Gaussians: {}\n'

'Residual error when fitting 2 Gaussians: {}'.format(err3, err2))

# Residual error when fitting 3 Gaussians: 3.52000910965

# Residual error when fitting 2 Gaussians: 3.82054499044

在這種情況下，3高斯給出了一個更好的結果，但我也使我的初步猜測相當準確。

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